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Metal casino12/8/2023 ![]() ![]() H2O and ZnF2, forming a robust SEI that results in uniform Zn2+ deposition and improved Zn2+ transport kinetics.Moreover, TFA, with a low LUMO value, breaks down into Zn4CO3(OH)6 The interaction between TFA and H2O disrupts the H bonds network structure of H2O, resulting in a reduction of active H2O and stabilization of the electrolyte’s pH value. The CO group of TFA interacts strongly with Zn2+, leading to a change in the inherent structure of Zn(H2O)62+ and an enhancement in the transport of Zn2+. ![]() ![]() Herein, we propose a solution to the issue of AZIBs by creating a versatile electrolyte through the addition of trifluoroacetamide (TFA). The practical application of aqueous zinc-ion batteries (AZIBs) is limited due to the inherent side reactions and dendrites growth of Zn anode. ![]()
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